Today - redox potentials in Rowan!

Single-electron chemistry is everywhere today. Photoredox, electrochemistry, Ni/Cu odd-electron catalysts... much new science involves adding or removing electrons to/from substrates. (Not to mention redox flow batteries, etc.)

Our total synthesis of (+)-randainin D and (+)-barekoxide via photoredox-catalyzed deoxygenative allylation is now out in J. Am. Chem. Soc.. You can find the article here: pubs.acs.org/doi/10.1021/ja…
#TotalSynthesis

organic-chemistry.org/abstracts/lit8…
A mild transition-metal- and photosensitizer-free photoredox system based on the combination of NaI and PPh3 for a highly selective reduction of nitroarenes

New co-first author paper out in J. Am. Chem. Soc. open access! 🔓 Caltech Chemistry & Chemical Engineering Ryan Hadt

💡First transient absorption on Ni(I) complexes

🧪One-step synthesis of Ni(I)-bpy halide

📉Unusual Marcus theory behavior

🚨Implications for photoredox catalysis

pubs.acs.org/doi/10.1021/ja…

Check out our latest in the Rxiv! A method for synthesizing a-tertiary amino acids using synergistic photoenzymatic catalysis between a PLP-dependent threonine aldolase and small-molecule photoredox catalyst. Congrats to Yao, Claire, and Catherine! chemrxiv.org/engage/chemrxi…

Photoredox-catalyzed synthesis of α,α-difluoromethyl-β-alkoxysulfones from sulfur dioxide

doi.org/10.1016/j.ccle…

organic-chemistry.org/abstracts/lit9…
A visible-light photoredox-catalyzed decarboxylation of α-oxo carboxylic acids in the presence of D2O

It does not always have to be rhodium: Anurag and Viktor demonstrate iron(III)-organo-photoredox catalyzed hydroformylations, hydroacylations and hydrocarboxylations of electron deficient alkenes. Out in Tetrahendron Chem: doi.org/10.1016/j.tche…

Check out our most recent preprint: Decarboxylative C N coupling of 2,2-difluorobicyclo[1.1.1]pentane (BCP-F2) building blocks on ChemRxiv!
It was a privilege to work with my colleague Joanna and summer intern Bryce Gaskins #MerckChemistry #BCP #photoredox
go.shr.lc/3tjsj4j

For the chemical biology seminar today, we get to hear from our very own David Cabañero as he tells us about some fantastic work on protein labeling using carbenes and deep red photoredox catalysis! #itsgivingshortlifetime #itsgivingspatiotemporalcontrol

Tuning Photoredox Catalysis of Ruthenium with Palladium: Synthesis of Heterobimetallic Ru–Pd Complexes That Enable Efficient Photochemical Reduction of CO2

J. Am. Chem. Soc. #Chemistry #Chemed #Science #TechnologyNews #news #technology #AcademicTwitter

pubs.acs.org/doi/10.1021/ja…

Dunkin sensing I'm in a photoredox mood. This drink is serving Eosin Y couture

Total Synthesis of the Diterpenes (+)-Randainin D and (+)-Barekoxide via Photoredox-Catalyzed Deoxygenative Allylation

J. Am. Chem. Soc. #Chemistry #Chemed #Science #TechnologyNews #news #technology #AcademicTwitter #AcademicChatter

pubs.acs.org/doi/10.1021/ja…

Do you like alcohol(s)? Have a look at this Facile in batch and flow photoredox C1 to Cn hydroxyhomologation for the introduction of hydroxyalkyl motif in molecular structures. Luisi-Lab, SusPharma, Francesco Pasca, Yuri Gelato , Michael Andresini
chemrxiv.org/engage/chemrxi…

Copper-catalyzed photoredox 1,4-amidocyanation of 1,3-enynes with N-amidopyridin-1-ium salts and TMSCN: Facile access to α-amido allenyl nitriles

doi.org/10.1016/j.ccle…

Chemicals, often misunderstood, are essential for medicines, fuels, and everyday items. 💊⚗️

#ColoradoState 's new Center for Sustainable Photoredox Catalysis will explore how light can be used to make more sustainable chemicals. 🧪💡 col.st/ftBIA

Multiphoton photoredox catalysis enables selective hydrodefluorinations Magnus Rueping

doi.org/10.1016/j.ccle…

A [delayed] big congrats to Penn State Chemistry PhD #5, Dr. Steve Huss Steven Huss! Steve started working on the nanothread project with John Badding and then continued those efforts in our group, while also working in photoredox catalysis. Steve started a job DuPont 🥳🙌🍾

Luminescent and Photoredox-Active Molybdenum(0) Complexes Competitive with Isoelectronic Ruthenium(II) Polypyridines

Tao Jin and Dorothee Wagner in Angewandte Chemie

onlinelibrary.wiley.com/doi/10.1002/an…

Enantioselective Construction of Quaternary Stereocenters via Cooperative Photoredox/Fe/Chiral Primary Amine Triple Catalysis

J. Am. Chem. Soc. #Chemistry #Chemed #Science #TechnologyNews #news #technology #AcademicTwitter #AcademicChatter

pubs.acs.org/doi/10.1021/ja…